Direct shaping of oxides by laser insolation of transition metal oxalates

Films of copper and cobalt-iron oxalates were prepared from suspensions of powders in ethane-1,2-diol deposited on glass or polycarbonate substrates. Two-dimensional structures of oxides, resolved on the scale of less than ten micrometers, were formed by laser insolation of these films, using a photolithog- raphy machine. The nature of the constitutive phases of the oxides formed tends to show that the laser heating makes it possible to reach locally, temperatures higher than 1000 ◦ C. The oxides formed are thus sintered. The residual oxalate can be removed by washing or dissolving, leaving the oxide structure on its substrate. In spite of a perfectible sintering, the formed structures could interest different technological applications (electronic or magnetic devices, gas sensors, photovoltaic systems. . .) requiring the shaping of simple or mixed oxides on a scale close to the micrometer. The process of selective laser decomposition of oxalates, could subsequently be suitable for additive manufacturing of 3D parts.

Various two dimensional structures formed in a film of copper oxalate deposited on polycarbonate substrate:(a) grid of pitch100 micrometers (b)structure inspired by RF circuits.

More informations : Direct shaping of oxides by laser insolation of transition metal oxalates I. Pasquet, H. Le Trong, V. Baco-Carles, L. Presmanes, C. Bonningue, V. Baylac, Ph. Tailhades, V. Conedera, P.F Calmon, D. Dragomirescu, H. Camon. Journal of the European Ceramic Society 37 (2017) 5315–5320